We examine the theoretical motivations for long-lived particle (LLP) signals at the LHC in a comprehensive survey of standard model (SM) extensions. LLPs are a common prediction of a wide range of theories that address unsolved fundamental mysteries such as naturalness, dark matter, baryogenesis and neutrino masses, and represent a natural and generic possibility for physics beyond the SM (BSM). In most cases the LLP lifetime can be treated as a free parameter from the mu m scale up to the Big Bang...
Generalized convulsive status epilepticus (GCSE) represents the most clinically dramatic and life-threatening type of status epilepticus, characterized either by continuous generalized tonic–clonic convulsive seizures or by repetitive bilateral convulsive seizures without recovery to functional baseline in the interictal periods. Although GCSE can emerge from partial seizures or partial status epilepticus, and the convulsions typically decrease by frequency and intensity over time, the widespread...
The history of electroencephalography (EEG) began in the late 1800s and has increasingly led to clinical, experimental, and computational studies that have enabled the discovery, understanding, recognition, diagnosis, and treatment of a great number of neurophysiological abnormalities and critical illnesses of the brain and spinal cord. Currently, EEGs are often continuously recorded mostly using scalp or cortical electrodes with enough digital EEG memory to store extended recordings of several hours....
Waveguide-based spin-photon interfaces on the GaAs platform have emerged as a promising system for a variety of quantum information applications directly integrated into planar photonic circuits. The coherent control of spin states in a quantum dot can be achieved by applying circularly polarized laser pulses that may be coupled into the planar waveguide vertically through radiation modes. However, proper control of the laser polarization is challenging since the polarization is modified through...
We derive a closed-form expression for the weak localization (WL) corrections to the magneto-conductivity of a 2D electron system with arbitrary Rashba alpha and Dresselhaus beta (linear) and beta(3) (cubic) spin-orbit interaction couplings, in a perpendicular magnetic field geometry. In a system of reference with an in-plane (z) over cap axis chosen as the high spin-symmetry direction at alpha = beta, we formulate a new algorithm to calculate the three independent contributions that lead to WL....
We employed ab initio global structural prediction algorithms to obtain the ground-state structure of CuBO2 This is a very promising p-type transparent conductive oxide that was synthesized recently, and thought to belong to the delafossite family. We proved that the true ground state is certainly not the delafossite structure, and that the most promising candidate is a low symmetry monoclinic phase. This is still a layered structure, but with boron and copper having a different coordination with...
An algorithm for fast calculation of the Coulombic forces and energies of point particles with free boundary conditions is proposed. Its calculation time scales as N log N for N particles. This novel method has lower crossover point with the full O(N-2) direct summation than the fast multipole method. The forces obtained by our algorithm are analytical derivatives of the energy which guarantees energy conservation during a molecular dynamics simulation. Our algorithm is very simple. A version of...
Interpolating scaling functions give a faithful representation of a localized charge distribution by its values on a grid. For such charge distributions, using a fast Fourier method, we obtain highly accurate electrostatic potentials for free boundary conditions at the cost of O(N log N) operations, where N is the number of grid points. Thus, with our approach, free boundary conditions are treated as efficiently as the periodic conditions via plane wave methods. (c) 2006 American Institute of Physics.
Silicon nanowires inspire since decades a great interest for their fundamental scientific importance and their potential in new technologies. When decorated with organic molecules they form hybrid composites with applications in various fields, from sensors to life science. Specifically the diethyl 1-propylphosphonate/Si combination is considered as a promising alternative to the conventional semiconductor n-type doping methods, thanks to its solution-based processing, which is damage-free and intrinsically...
Scalable quantum technologies such as quantum computers will require very large numbers of quantum devices to be characterised and tuned. As the number of devices on chip increases, this task becomes ever more time-consuming, and will be intractable on a large scale without efficient automation. We present measurements on a quantum dot device performed by a machine learning algorithm in real time. The algorithm selects the most informative measurements to perform next by combining information theory...
Mobile single interstitials can grow into extended interstitial defect structures during thermal anneals following ion implantation. The silicon tetra-interstitials present an important intermediate structure that can either provide a chain-like nucleation site for extended structures or form a highly stable compact interstitial cluster preventing further growth. In this paper, dimer searches using the tight-binding (TB) model by Lenosky et al. and density functional calculations show that the compact...
Using the minima hopping global geometry optimization method on density functional potential energy surface, we have studied the structural and electronic properties of magnesium clusters for a size range of Mg-N where N = 10-56. Our exhaustive search reveals that most of our global minima are nonsymmetric in the size range above N = 20. We elucidate the evolutionary trend of the entire series and present more details about the peculiar growth of the clusters. For N> 20, it is possible to divide...
Key to single-molecule electronics is connecting functional molecules to each other using conductive nanowires. This involves two issues: how to create conductive nanowires at designated positions, and how to ensure chemical bonding between the nanowires and functional molecules. Here, we present a novel method that solves both issues. Relevant functional molecules are placed on a self-assembled monolayer of diacetylene compound. A probe tip of a scanning tunneling microscope is then positioned on...
In this contribution we will describe in detail a Density Functional Theory method based on a Daubechies wavelets basis set, named BigDFT. We will see that, thanks to wavelet properties, this code shows high systematic convergence properties, very good performances and an excellent efficiency for parallel calculations. BigDFT code operation are also well-suited for GPU acceleration. We will discuss how the problematic of fruitfully benefit of this new technology can be match with the needs of robustness...
An efficient numerical quadrature is proposed for the approximate calculation of the potential energy in the context of pseudo potential electronic structure calculations with Daubechies wavelet and scaling function basis sets. Our quadrature is also applicable in the case of adaptive spatial resolution. Our theoretical error estimates are confirmed by numerical test calculations of the ground state energy and wavefunction of the harmonic oscillator in one dimension with and without adaptive resolution....
Organic electronics require a precise control over properties of a moleculeâEuro"substrate interface as well as film growth morphology, from both fundamental points of view, when a clean vacuum environment is needed and also under ambient air conditions. In this paper, we present submonolayer molecular films of para-hexaphenyl (6P) formation on the rutile TiO2(110) substrates and ways of affecting the growth and morphology via ion-beam nanopatterning. Ultrahigh vacuum deposition and measurements...
The NaCl(001) surface was investigated by friction force microscopy in ultra-high vacuum conditions at room temperature. A homemade atomic force microscope was used which allows an in situ sample rotation. With this ability, it is not only possible to measure friction along arbitrary orientations of the NaCl crystal, but also the symmetry directions of the sample can be precisely tuned parallel to the scan orientation which is fixed orthogonal to the cantilever axis for a calibrated friction measurement....
Majorana fermions have recently garnered a great attention outside the field of particle physics, in condensed matter physics. In contrast to their particle physics counterparts, Majorana fermions are zero energy, chargeless, spinless, composite quasiparticles, residing at the boundaries of so-called topological superconductors. Furthermore, in opposition to any particles in the standard model, Majorana fermions in solid-state systems obey non-Abelian exchange statistics that make them attractive...
Why sex chromosomes turn over and remain undifferentiated in some taxa, whereas they degenerate in others, is still an area of ongoing research. The recurrent occurrence of homologous and homomorphic sex chromosomes in distantly related taxa suggests their independent evolution or continued recombination since their first emergence. Fishes display a great diversity of sex-determining systems. Here, we focus on sex chromosome evolution in haplochromines, the most species-rich lineage of cichlid fishes....
The impressive adaptive radiation of notothenioid fishes in Antarctic waters is generally thought to have been facilitated by an evolutionary key innovation, antifreeze glycoproteins, permitting the rapid evolution of more than 120 species subsequent to the Antarctic glaciation. By way of contrast, the second-most species-rich notothenioid genus, Patagonotothen, which is nested within the Antarctic clade of Notothenioidei, is almost exclusively found in the non-Antarctic waters of Patagonia. While...
Differential gene expression can be translated into differing phenotypic traits. Especially during embryogenesis, specific gene expression networks regulate the development of different body structures. Cichlid fishes, with their impressive phenotypic diversity and propensity to radiate, are an emerging model system in the genomics era. Here we set out to investigate gene expression throughout development in the well-studied cichlid fish Astatotilapia burtoni, native to Lake Tanganyika and its affluent...
Objectives:; Since 2002, Swiss community pharmacists have dispensed emergency contraception (EC) as pharmacist-only medicine ideally using the official Swiss protocol. Our study aimed to determine pharmacists' resolution of an imaginary EC case, compliance with the protocol, and provision of information on the risk of sexually transmitted infections (STIs).; Methods:; We conducted a simulated patient study with 69 students who each visited a community pharmacy. The scenario started with the student...
Pharmacist-led cognitive services (PLCS) are increasingly necessary in primary care as a response to patient-centered care. However, the implementation rate and remuneration models of PLCS are either absent or superficially described in the literature.; The aim of this study is to review the implementation of PLCS in primary care across Europe and explore the associated third-party paid remuneration models.; A cross-sectional study was conducted using an online survey sent to representatives of 44...
Selecting peer reviewers is a crucial stage of the editorial process that ensures the quality of scholarly publications. An alternative to selecting peer reviewers from data bases created with expressions of interest of volunteers consists in systematically searching PubMed for similar articles and inviting their authors to act as peer reviewers. Although this process might identify more appropriate peers, it also can increase the time of the editorial process. In 2018, Pharmacy Practice had to invite...
Investigation of organic compounds in ice cores can potentially unlock a wealth of new information in these climate archives. We present results from the first ever ice core drilled on sub-Antarctic island Bouvet, representing a climatologically important but understudied region. We analyze a suite of novel and more familiar organic compounds in the ice core, alongside commonly measured ions. Methanesulfonic acid shows a significant, positive correlation to winter sea ice concentration, as does a...
Highly oxygenated molecules (HOMs) play an important role in the formation and evolution of secondary organic aerosols (SOA). However, the abundance of HOMs in different environments and their relation to the oxidative potential of fine particulate matter (PM) are largely unknown. Here, we investigated the relative HOM abundance and radical yield of laboratory-generated SOA and fine PM in ambient air ranging from remote forest areas to highly polluted megacities. By electron paramagnetic resonance...
Real-time, online measurements of atmospheric organic aerosol (OA) composition are an essential tool for determining the emissions sources and physicochemical processes governing aerosol effects on climate and health. However, the reliance of current techniques on thermal desorption, hard ionization, and/or separated collection/analysis stages introduces significant uncertainties into OA composition measurements, hindering progress towards these goals. To address this gap, we present a novel, field-deployable...
The Atmospheric Pollution and Human Health in a Chinese Megacity (APHH-Beijing) programme is an international collaborative project focusing on understanding the sources, processes and health effects of air pollution in the Beijing megacity. APHH-Beijing brings together leading China and UK research groups, state-of-the-art infrastructure and air quality models to work on four research themes: (1) sources and emissions of air pollutants; (2) atmospheric processes affecting urban air pollution; (3)...
This study presents the molecular composition of organic aerosol (OA) using ultra-high-resolution mass spectrometry (Orbitrap) at an urban site in Central Europe (Zurich, Switzerland). Specific source spectra were also analysed, including samples representative of woodburning emissions from Alpine valleys during wood-burning pollution episodes and smog chamber investigations of woodsmoke, as well as samples from Hyytiala, which were strongly influenced by biogenic secondary organic aerosol. While...
The cuticle, the outermost layer covering the epidermis of most aerial organs of land plants, can have a heterogeneous composition even on the surface of the same organ. The main cuticle component is the polymer cutin which, depending on its chemical composition and structure, can have different biophysical properties. In this study, we introduce a new on-surface depolymerization method coupled to liquid extraction surface analysis (LESA) high-resolution mass spectrometry (HRMS) for a fast and spatially...
Many atmospheric organic compounds are long-lived enough to be transported from their sources to polar regions and high mountain environments where they can be trapped in ice archives. While inorganic components in ice archives have been studied extensively to identify past climate changes, organic compounds have rarely been used to assess paleo-environmental changes, mainly due to the lack of suitable analytical methods. This study presents a new method of direct injection high performance liquid...
Aerosol particles and their interactions with clouds are one of the most uncertain aspects of the climate system. Aerosol processing by clouds contributes to this uncertainty, altering size distributions, chemical composition, and radiative properties. Many changes are limited by the availability of hydroxyl radicals in the droplets. We suggest an unrecognized potentially substantial source of OH formation in cloud droplets. During the first few minutes following cloud droplet formation, the material...
The majority of atmospheric compounds measured in ice cores are inorganic, while analysis of their organic counterparts is a less well developed field. In recent years, understanding of formation, transport pathways and preservation of these compounds in ice and snow has improved, showing great potential for their use as biomarkers in ice cores. This study presents an optimised analytical technique for quantification of terrestrial and marine biosphere emissions of secondary organic aerosol (SOA)...
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