Environmental Science and Pollution Research

Correction to: High efficiency inactivation of microalgae in ballast water by a new proposed dual-wave UV-photocatalysis system (UVA/UVC-TiO 2 ) In the third paragraph of Introduction, the sentence “Few scholars have conducted static studies on dual-wavelength UV photocatalytic technologies (Ma 2018)”.

Size-specific responses of the amphipod Eohaustorius estuarius to clay in sediment toxicity testing Abstract A number of lines of evidence suggest that the amphipod Eohaustorius estuarius has variable tolerance to clay in sediments. In the current study, two laboratory dose-response experiments were conducted with kaolin clay to evaluate whether clay effects varied with amphipod size. The results indicated that smaller amphipods (< 0.9 mg dry wt.) were significantly more tolerant of clay than larger individuals up to 2.9 mg dry wt. Average survival in clay/sand mixtures with > 70% clay was 88%, 71%, and 52% for small (0.6–1.2 mg), medium (1.4–1.9 mg), and large (1.8–2.9 mg) amphipods, respectively. Standard 96-h reference toxicant tests with cadmium chloride (CdCl2) were conducted to determine whether there were size-specific differences in response to this metal reference toxicant. The CdCl2 median lethal concentrations (LC50s) for small, medium, and large amphipods were 6.78, 5.13, and 4.63 mg/L, respectively. Responses of all three size classes to cadmium were within historic confidence intervals for this reference metal, and were not significantly different from one another based on overlapping confidence intervals. Additional experiments with high clay reference site sediments from San Francisco Bay were conducted to confirm the size-related response with field sediments, but were only partially conclusive. Overall results suggest that the use of smaller amphipods in routine monitoring of high clay sediments will reduce the influence of this factor on test results.

Enhancing sustainable electricity consumption in a large ecological reserve–based country: the role of democracy, ecological footprint, economic growth, and globalisation in Brazil Abstract The objective of this study is to investigate the role of democracy, ecological footprint, economic growth, and globalisation in enhancing sustainable electricity consumption in an ecological reserve–based country of Brazil over the period 1971–2014. To achieve this objective, the minimum Lagrange multiplier (LM) unit root and Bayer–Hanck combined cointegration tests are applied. The model is estimated using the fully modified ordinary least squares (FM-OLS) and dynamic ordinary least squares (DOLS) estimation procedures. The empirical results suggest that all the variables have a positive and significant effect on electricity consumption. This implies that increasing the level of these variables would stimulate electricity consumption. The long-run causality results indicate a one-way causality running from ecological footprint, democracy, and globalisation to electricity consumption. The results further discover that causality flows from ecological footprint, democracy, and globalisation to economic growth. In addition, a long-run bidirectional causal relationship between electricity consumption and economic growth is uncovered. In the short run, the result validates a bidirectional causality between ecological footprint and electricity consumption. More so, electricity consumption causes economic growth and democracy, whilst economic growth causes globalisation. The results are validated by the innovation accounting tests. The policy implication of the findings is that ecological-based conservation policies could have negative consequences on economic growth and electricity consumption because of a significant dependence of these two variables on the ecological footprint. Therefore, to guarantee sustainable electricity consumption, sufficient and sustainable green energy and optimum energy mix should be encouraged by the stakeholders.

Heavy metal concentrations in roadside plants ( Achillea wilhelmsii and Cardaria draba ) and soils along some highways in Hamedan, west of Iran Abstract The present study was conducted to analyze the effects of traffic volumes on Cd, Cu, Pb, Ni, and Zn contents in roadside soils and in two dominant herbaceous species (Achillea wilhelmsii and Cardaria draba) along highways and to evaluate the dynamic characteristics of these elements and their accumulation by the aerial parts and roots of these herbaceous species. The plant samples were collected along 700 m of a 9-km segment of each of the three major highways in Hamedan Province (West Iran) with different traffic volumes: Hamedan-Goltapeh (HG), Hamedan-Razan (HR), and Hamedan-Kermanshah (HK). The results indicated that the mean contents of Cd, Cu, Pb, Ni, and Zn in the soil samples were 0.26, 18.74, 14.98, 18.21, and 62.25 mg kg−1, respectively. Furthermore, the mean contents of elements (mg kg−1) in aerial parts of A. wilhelmsii were 0.16 for Cd, 4.52 for Cu, 1.91 for Pb, 1.70 for Ni, and 44.80 for Zn, while in the aerial part samples of C. draba, the concentrations (mg kg−1) and the mean contents were 0.16, 2.29, 2.58, 1.60, and 31.29, respectively. This meant that the traffic volume affected the contents of the metals in the soil and the herbaceous species. The metal content in herbaceous tissues varied significantly between plant species. A. wilhelmsii tended to accumulate the metals in the roots while C. draba retained them mostly in the aerial parts. The significant positive correlations of Cd, Cu, Ni, and Zn content in root and aerial parts of the herbaceous plant with those found in the soil samples showed the potential of the studied species for application in biomonitoring studies. Comprehensive analysis (effect of traffic volumes and relationships between the content of elements in plant tissues and soil samples) indicated that Cu in both herbaceous plants was mainly derived from soil, while A. wilhelmsii absorbed Cd and C. draba absorbed Zn mainly through the stomata from atmospheric depositions. Without considering atmospheric depositions due to intense traffic volumes, in A. wilhelmsii, the translocation factor (TF) values of Cu and Zn were 1.06 and 1.44, respectively and in C. draba, the TF values of Cd, Cu, and Pb were 1.06, 1.09, and 1.13, respectively, thus suggesting that both herbaceous species had high potentials for transferring metals from the roots to aerial parts.

Selective and simultaneous detection of cadmium, lead and copper by tapioca-derived carbon dot–modified electrode Abstract The need for the sensing of environmental pollutants cannot be overemphasized in the twenty-first century. Herein, a sensor has been developed for the sensitive and selective detection of copper (Cu2+), lead (Pb2+) and cadmium (Cd2+) as major heavy metals polluting water environment. A screen-printed carbon electrode (SPCE) modified by fluorescent carbon dots (CDs) and gold nanoparticles (AuNPs) was successfully fabricated for sensing Cu2+, Pb2+ and Cd2+. Differential pulse voltammetry (DPV) and cyclic voltammetry (CV) were deployed for the analysis of ternary analytes. CV was set at a potential range of − 0.8 to + 0.2 V at a scan rate of 100 mV/s, and DPV at a potential range of − 0.8 to + 0.1 V, scan rate of 50 mV/s, pulse rate of 0.2 V and pulse width of 50 ms. DPV technique was applied through the modified electrode for sensitive and selective determination of Cu2+, Pb2+ and Cd2+ at a concentration range of 0.01 to 0.27 ppm for Cu2+, Pb2+ and Cd2+. Tolerance for the highest possible concentration of foreign substances such as Mg2+, K+, Na+, NO3−, and SO42− was observed with a relative error less than ± 3%. The sensitivity of the modified electrode was at 0.17, 0.42 and 0.18 ppm for Cd2+, Pb2+ and Cu2+, respectively, while the limits of detection (LOD) achieved for cadmium, lead and copper were 0.0028, 0.0042 and 0.014 ppm, respectively. The quality of the modified electrode for sensing Cu2+, Pb2+ and Cd2+ at trace levels is in accordance with the World Health Organization (WHO) and Environmental Protection Agency (EPA) water regulation standard. The modified SPCE provides a cost-effective, dependable and stable means of detecting heavy metal ions (Cu2+, Pb2+ and Cd2+) in an aqueous solution. Graphical abstract .

Emerging trends in municipal solid waste incineration ashes research: a bibliometric analysis from 1994 to 2018 Abstract The rapidly increasing generation of municipal solid waste (MSW) threatens the environmental integrity and well-being of humans at a global level. Incineration is regarded as a technically sound technology for the management of MSW. However, the effective management of the municipal solid waste incineration (MSWI) ashes remains a challenge. This article presents the global dynamics of MSWI ashes research from 1994 to 2018 based on a bibliometric analysis of 1810 publications (research articles and conference proceedings) extracted from the Web of Science database, followed by a comprehensive summary on the research developments in the field. The results indicate the rapid growth of annual publications on MSWI ashes research, with China observed as the most productive country within the study period. Waste Management, Journal of Hazardous Materials, Chemosphere and Waste Management & Research, which accounted for 35.42% of documents on MSWI research, are the most prominent journals in the field. The most critical thematic areas on this topic are MSWI ashes characterisation, dioxin emissions from fly ash, valorisation of bottom ash and heavy metal removal. The evolution of MSWI ashes treatment technologies is also discussed, together with the challenges and future research directions. This is the first bibliometric analysis on global MSWI ashes research based on a sufficiently large dataset, which could provide new insights for researchers to initiate further research with leading institutions/authors and ultimately advance this research field.

Effective decontamination of As(V), Hg(II), and U(VI) toxic ions from water using novel muscovite/zeolite aluminosilicate composite: adsorption behavior and mechanism Abstract Muscovite/phillipsitic zeolite was introduced as a novel inorganic composite of stunning adsorption properties. The composite was investigated in the uptake reactions of Hg(II), As(V), and U(VI) as highly toxic water contaminants considering different adsorption factors. The adsorption properties of muscovite/phillipsitic zeolite are highly dependent on the pH values and the best decontamination percentages can be obtained at pH 4, pH 5, and pH 5 for Hg(II), As(V), and U(VI), respectively. The kinetic studies demonstrated adsorption equilibrium for Hg(II), As(V), and U(VI) after 360 min, 300 min, and 360 min, respectively. The equilibrium modeling suggested monolayer uptake for all the metals and represented mainly by the Langmuir model considering both the values of determination coefficient and chi-squared (χ2). The estimated maximum capacities are 117 mg/g (Hg(II)), 122.5 mg/g (As(V)), and 138.5 mg/g (U(VI)) which are higher values than several studied adsorbents. The Dubinin–Radushkevich adsorption energies of Hg(II) (19.4 kJ/mol), As(V) (25.6 kJ/mol), and U(VI) (26.47 kJ/mol) signify chemical adsorption mechanisms and close to the obtained values for the ion-exchange process. Additionally, the composite is of high reusability properties and was applied effectively for five decontamination cycles. Graphical abstract

The using of the Index of Ideality of Correlation (IIC) to improve predictive potential of models of water solubility for pesticides Abstract Models for water solubility of pesticides suggested in this manuscript are important data from point of view of ecologic engineering. The Index of Ideality of Correlation (IIC) of groups of quantitative structure–property relationships (QSPRs) for water solubility of pesticides related to the calibration sets was used to identify good in silico models. This comparison confirmed the high IIC set provides better statistical quality of the model for the validation set. Though there are large databases on solubility, the reliable prediction of the endpoint for new substances which are potential pesticides is an important ecologic task. Unfortunately, predictive models for various endpoints suffer overtraining, and the IIC serves to avoid or at least reduce this. Thus, the approach suggested has both theoretical and economic effects for ecology.

West Africa’s CO 2 emissions: investigating the economic indicators, forecasting, and proposing pathways to reduce carbon emission levels Abstract This paper investigates the nexus between carbon emissions (CO2) and economic growth in West Africa based on the Environment Kuznets Curve (EKC) hypothesis by utilizing spatial panel data technique to check the possible effect of spatial dependence among countries in West Africa. Our empirical findings suggest the presence of spatial dependence of carbon emissions distribution in West Africa. By examining the existence of EKC embedded within the Stochastic Impacts by Regression on Population, Affluence, and Technology (STIRPAT) approach, we conclude an inverse N-trajectory of the relationship between carbon emissions and economic growth. Furthermore, to mitigate global carbon emissions, we utilize a recurrent neural network (RNN) bidirectional long short-term memory (BiLSTM) algorithm devoid of exogenous variables and assumptions to forecast carbon emissions from the year 2015 to the year 2030 based on the predictive accuracy of our formulated algorithm. Due to the upward trends in future emission levels, we propose emissions mitigation pathways for countries in West Africa to still hold carbon emissions-related global warming well below 1.5 and 2 °C. Such mitigation pathways proposed could help implement strategic policies to minimize carbon emissions to a considerable level. As a policy implication, drafting strict environmental regulations and utilizing renewable energy technologies will help mitigate carbon emissions for all West African countries.

Evaluation of automotive shredder residues (ASR) landfill behavior through lysimetric and traditional leaching tests Abstract With regards to European waste catalog, automotive shredder residues (ASR) can be classified both as a hazardous or non-hazardous waste according to its hazardous properties (H1–H14). It is thus important to carry out an adequate chemical-physical characterization to identify the presence and concentration of those substances able to give, to this extremely heterogeneous material, the hazardousness character of. The issue of waste characterization, to identify the proper site for appropriate waste disposal, is based, according to the relevant laws, to the use of leaching tests. The analysis of the potential effects of landfilled waste in laboratory, however, run into several difficulties in reproducing phenomena depending both on the characteristics of small, heterogeneous quantity of waste and on the local boundary conditions. These difficulties are much more significant as the waste is heterogeneous at the small scale of the laboratory. This is one of the main problems often leading to scattered results even when starting from the same waste parcel. Present research aimed to overcome the above-mentioned difficulties deriving from waste heterogeneity and was based on a lysimetric simulation. Experimentation with lysimeter has shown it effectiveness in the comparison between leachate from the lysimeter and an ASR landfill leachate, from which similar distribution of metal mass ratios, close values for both BOD5 and COD, as well as the absence in both the fluids of organochlorinated compounds, emerge.